I have run xylene and 93 oct pump gas for quite some time with 0 problems. I will admit that I have never tried the equiv of straight gas that was made mixed at the same octane I run. Before I started doing it I read as much as I could. Don't ask me to quiote specifics, it has been a couple of years, but for the most part higher octane gas is made by adding xylene. Your milage and local brand's formula will vary. There is a lot of good info and links over in the tech/fuel section at gnttype.org.
If it is worth anything I run a mixed 97 octane using quality 93 oct. pump + xylene and a little trans fluid.
Brent