That won't work. You should set the rotor phasing first anyways. The problem is that rotor phasing and cam sync should not be related, but in a distributor they are as a compromise.
Rotor phasing is most important so set that first. You want the rotor to be pointed at the right terminal on the cap when your motor is making power. 20 degrees is a close enough number. Even if you are running bank to bank, you still have to set the phasing correctly. Once you get the rotor phased, the distributor does not need to move anymore, so lock it in place.
Next is the cam sync. It has a wide range that is acceptable. Minimum 15 degrees before the crank trigger, but less than 120. It can be in before any cylinder firing, but to simplify, use those numbers. Preferably, you would have the reluctor adjustable, but since there is a big window it's not always necessary. As long as it's between 15 before the crank reference and less than 120 you are good. It it's off, you have to move it so that it is. This requires you disassemble the distributor. Then you have to start over each time you pull it and move it.
I can describe how to move it, but it's a lot of trouble and yours should already be ok if it came off a running motor. So recheck it and see where it's at fist.