Difference
Auto A/C systems are designed to be the most efficent while driving. The faster the engine turns, the more the compressor pumps.
A car moving at 35 to 40 mph, at about 1500rpm, with good air flow through the condensor, will be working at it's best. At idle the system is working at it's minimum.
When testing you want to make sure you have a fan blowing air through the condensor, 1500rpm, windows closed, controls at max and fan on medium, A/C gauges attached. Depending on the outside temp, the low gauge should go down to 25 and the high shouldn't go over 300. If the high is starting to get close, mist some water on the condensor, it should go down right away. The cooler the condensor is, the cooler the vent air will be. If everything else is working properly.