There is a pressure gauge there so you should be able to push the button and have someone tell you what the pressure gauge reads but I would bet that old SMC kit is your problem. Alky is great when it's working properly but many people don't like it because the pumps will fail and when they do severe engine damage will occur if you continue to drive it like it's working. The Alky Control kit is a awesome kit and even with it you can expect to buy a new pump every couple years.
So for now you can lower the boost down to about 16 psi and take about 3 degrees of timing out of all of the chip settings for 1/2 and 3/4 by making adjustments in the chip assuming it's a newer version that is adjustable or you can buy a non alky chip (if you're running 42# injectors I may even have an old chip you can have) or you can upgrade to a new Alky system. Of course you could try to use that SMC kit you have and just buy a new pump (just a guess at what's bad) but since this could cost you $5k to rebuild your engine if it fails at 23 psi of boost I wouldn't recommend that.
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