My air controls are doing exactly the same thing except they don't fix themselves after running.
Took it to Buick and they converted the AC to the current freon and found a couple of vacuum hoses that needed attention.
They said it worked perfectly...and even did the temperature check using the vents (55 degrees...not bad for a 25 year old compressor). I picked up the car last night...no air flow out of the vents and the service guys were already gone. I called them today but they couldn't look at it....ba$tards....so I will have to take it back during the week. They did let me talk to the tech and he walked me through his work and it looks fine.
I took the climate controls out of the dash and everything looks hooked up, and not pinched. I even tried the vents with the controls hanging out of the dash just in case they were getting pinched after cramming everything back into its small space. I'm stumped but I'm not that great of a mechanic so its a familiar feeling! :redface:
SteveV mentions vaccum switches but I don't know where those are located on the car. I could take it back to Buick and probably will but wanted to take a swing at it myself do avoid the hassle.