Sherwin Williams
Gallon containers
Reducer - Methanol R6K1
Sales Number
520-1199
Product Number UPC
R06K00001 ~
Size
GALLON
MATERIAL SAFETY DATA SHEET
R6K1
13 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER DATE OF PREPARATION HMIS CODES
Health 3
R6K1 30-SEP-07 Flammability 3
Reactivity 0
PRODUCT NAME
Methanol
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Regulatory Information
(216) 566-2902
Medical Emergency
(216) 566-2917
Transportation Emergency for Chemical Emergency ONLY (spill, leak,
(800) 424-9300 fire, exposure, or accident)
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
100 67-56-1 Methanol
ACGIH TLV 200 ppm (Skin) 92 mm
ACGIH TLV 250 ppm (Skin) STEL
OSHA PEL 200 ppm (Skin)
OSHA PEL 250 ppm (Skin) STEL
Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
Contains alcohols and acetates which can be absorbed through the skin.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
Continued on page 2
R6K1 page 2
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT LEL UEL
50 F PMCC 6.0 36.5
FLAMMABILITY CLASSIFICATION
RED LABEL -- Flammable, Flash below 100 F (38 C)
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
DOL Storage Class IB
Continued on page 3
R6K1 page 3
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are FLAMMABLE. Keep away from heat, sparks, and open flame.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PROTECTIVE EQUIPMENT
Use of barrier cream on exposed skin is recommended.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 6.56 lb/gal 786 g/l
SPECIFIC GRAVITY 0.79
BOILING POINT 148 - 150 F 64 - 65 C
MELTING POINT Not Available
VOLATILE VOLUME 100 %
EVAPORATION RATE Slower than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
6.56 lb/gal 786 g/l Less Water and Federally Exempt Solvents
6.56 lb/gal 786 g/l Emitted VOC
Continued on page 4
R6K1 page 4
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
TOXICOLOGY DATA
CAS No. Ingredient Name
67-56-1 Methanol
LC50 RAT 4HR 64000 ppm
LD50 RAT 5630 mg/kg
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Continued on page 5
R6K1 page 5
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
1 Quart and Less may be Classed as CONSUMER COMMODITY, ORM-D
Larger Containers are Regulated as:
UN1230, METHANOL, 3, PG II, (ERG#131)
DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities
Methanol 5000 lb RQ
Bulk Containers may be Shipped as (check reportable quantities):
UN1230, METHANOL, 3, PG II, (ERG#131)
Canada (TDG)
UN1230, METHANOL, CLASS 3, PG II, (ERG#131)
IMO
UN1230, METHANOL, CLASS 3, (6.1), PG II, (10 C c.c.), EmS F-E, S-D
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
67-56-1 Methanol 100
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information