The factory computer does not "control" boost. It simply pulses the wastegate solenoid a certain % duty cycle. Buick set it up knowing that X% = 14psi boost. The computer doesn't know what the actual boost is.
Depending on what kind of chip you bought, we change the wastegate duty cycle to increase boost. An alcohol chip and race chip will be max duty cycle (100%), and the user is expected to adjust the boost themselves using the wastegate actuator, or some other method (like a bleeder). For a street chip, I usually set the wastegate solenoid to pulse at a rate that would give roughly 17psi (assuming a stock wastegate and somewhat stock car).
In general, the user is expected to adjust/control the boost, since the computer can't. If you changed the chip and the boost went up, then you most likely are still using the factory solenoid, and the new chip is commanding a higher WG DC.
What is your chip# (order#) and I can look up your chip program.
Regards,
Eric