Thats a fairly long answer but here is a synopsis, Ill go into more detail when I do it on the GN. So there is 2 main products everyone calls "dynamat". 1. is a tar based product with an aluminum backing, that is generic dynamat and basically the same stuff you can buy for 1/4 the price at home depot and its called "peel and seal". 99% of people are ok with that. The only problem is in vegas when it gets hot it smells like asphalt because thats what its basically made of. 2. is a butyl based product like dynamat extreme or second skin. It has no smell and actually reduces more of the vibration
Now you mentioned cadillac quietness... That would require some more work. Basically dynamat or damplifier only reduce vibration based noises in a vehicle by adding mass to panels that resonate. You have to step it up a notch and get open cell and close celled foam to handle the high and low range harmonics that just pass right through those panels. Second skin sells both. You lay them down over the damplifier to do that. Here is a link to my corvette where I did that and I've also done this combo on a 1972 camaro, both times a day and night difference.
Help me quite down a 2006 Corvette! - Second Skin Forums
Just in case you dont want to read the thread here are the results on my 2006 corvette
Before
Idle : 76-80 db
30mph: 90-96 db
75mph: 102-107 db!!!
After
Idle : 71-73 db
30mph: 73-78 db
75mph: 75-82 db
Keep in mind that every 3 decibels is considered 2x as loud is almost an unreal change but that results from everything possible being done