If you get the 4 position quick tune option that is available, you can have your cake and eat it too. Run 91+alky on the street on one tune, flip the switch, turn up the boost, and run race fuel+alky. You can get specific tunes for whatever application you are running.
I got my XFI from Cal Hartline, give him a call, he is very helpful with answering questions, big or small and he doesn't "talk over your head" when explaining the system. I pretty much had the same questions you have when I bought mine.
Honestly, I wish I had bought this system a long time ago, most likely would have saved multiple head gaskets, a complete motor, and many headaches from jacking with the stock computer/tune.